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Planar
Defects
Stacking Faults and Twin Boundaries
A disruption of the long-range stacking sequence can produce two
other common types of crystal defects: 1) a stacking fault and
2) a twin region. A change in the stacking sequence over a few
atomic spacings produces a stacking fault whereas a change over
many atomic spacings produces a twin region.
A stacking fault is a one or two layer interruption in the stacking
sequence of atom planes. Stacking faults occur in a number of
crystal structures, but it is easiest to see how they occur in
close packed structures. For example, it is know from a previous
discussion that face centered cubic (fcc) structures differ from
hexagonal close packed (hcp) structures only in their stacking
order. For hcp and fcc structures, the first two layers arrange
themselves identically, and are said to have an AB arrangement.
If the third layer is placed so that its atoms are directly above
those of the first (A) layer, the stacking will be ABA. This is
the hcp structure, and it continues ABABABAB. However it is possible
for the third layer atoms to arrange themselves so that they are
in line with the first layer to produce an ABC arrangement which
is that of the fcc structure. So, if the hcp structure is going
along as ABABAB and suddenly switches to ABABABCABAB, there is
a stacking fault present.
Alternately, in the fcc arrangement the pattern is ABCABCABC.
A stacking fault in an fcc structure would appear as one of the
C planes missing. In other words the pattern would become ABCABCAB_ABCABC.
If a stacking fault does not corrects itself immediately but
continues over some number of atomic spacings, it will produce
a second stacking fault that is the twin of the first one. For
example if the stacking pattern is ABABABAB but switches to ABCABCABC
for a period of time before switching back to ABABABAB, a pair
of twin stacking faults is produced. The red region in the stacking
sequence that goes ABCABCACBACBABCABC
is the twin plane and the twin boundaries are the A planes on
each end of the highlighted region.
Grain Boundaries in Polycrystals
Another type of planer defect is the grain boundary. Up to this
point, the discussion has focused on defects of single crystals.
However, solids generally consist of a number of crystallites
or grains. Grains can range in size from nanometers to millimeters
across and their orientations are usually rotated with respect
to neighboring grains. Where one grain stops and another begins
is know as a grain boundary. Grain boundaries limit the lengths
and motions of dislocations. Therefore, having smaller grains
(more grain boundary surface area) strengthens a material. The
size of the grains can be controlled by the cooling rate when
the material cast or heat treated. Generally, rapid cooling produces
smaller grains whereas slow cooling result in larger grains. For
more information, refer to the discussion on solidification.
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